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The following relationship was derived for the gross reaction rate.

rbr=kp(kdkt)12[I.]12[M.]rbr = Gross reaction speedkp = Rate constant of the growth reactionkd = Rate constant of initiator decaykt = Rate constant of the termination[I.] = Initiator concentration[M.] = Monomer concentration

As the gross reaction rates for the polymerizations with full initiator concentration [I.]1and 25% initiator concentration [I.]2=14[I.]1should be the same, the following equation must apply.

kp(kdkt)12[I.]112[M.]1=kp(kdkt)12[I.]212[M.]2[M.]1= original monomer concentration[M.]2 = wanted monomer concentration

It follows:


Dissolve after [M.]2results


Video: The Solution. Craig Bierlys Wanderlust Way (July 2022).


  1. Sazshura

    Competent point of view, it is curious.

  2. Gaynor

    I do not need such good!

  3. Moogujin

    What necessary words ... Great, remarkable thought

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